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That's really an interesting question to me because I think it would be a very contextual choice for her. When writing her after her last appearance on Smallville, I think it depends on how much you think she'd want to superhero it up now. If it's something she's going to pursue seriously, I can see her taking her time before deciding on what sort of civilian life to settle into. She has plenty resources post-Lex to take the time to think it through at length, and there's so much baggage there for her to sort through. Closing the door permanently on Clark/Lana closes the door on a lot of other things in a very final way, I can't see her rebounding into a new life/career quickly after that. Given some time though, I think she'd want to revisit some lost threads of her past. Maybe something linked to her art school attempt, or something on a very local business level like what she did with the Talon. Given her opinions about Clark and his destiny, I can't see her taking on a career that would hamper her use of her new abilities to do good but I think she'd be a lot more successful at choosing something meaningful to do in her spare time and nurture her own emotional well-being than Clark has been.